Page:Popular Science Monthly Volume 4.djvu/298

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284
THE POPULAR SCIENCE MONTHLY.

in gases, but by no means in the same proportion. The same amount of motion takes about ten times as long to subside in water as in air, as you will see by what takes place when I stir these two jars, one containing water and the other air. There is still less difference between the rates at which a rise of temperature is propagated through a liquid and through a gas.

In solids the molecules are still in motion, but their motions are confined within very narrow limits. Hence, the diffusion of matter does not take place in solid bodies, though that of motion and heat takes place very freely. Nevertheless, certain liquids can diffuse through colloid solids, such as jelly and gum, and hydrogen can make its way through iron and palladium.

We have no time to do more than mention that most wonderful molecular motion which is called electrolysis. Here is an electric current passing through acidulated water, and causing oxygen to appear at one electrode, and hydrogen at the other. In the space between, the water is perfectly calm, and yet two opposite currents of oxygen and of hydrogen must be passing through it. The physical theory of this process has been studied by Clausius, who has given reasons for asserting that in ordinary water the molecules are not only moving, but every now and then striking each other with such violence that the oxygen and hydrogen of the molecules part company, and dance about through the crowd, seeking partners which have become dissociated in the same way. In water these exchanges produce, on the whole, no observable effect, but no sooner does the electromotive force begin to act, than it exerts its guiding influence on the unattached molecules, and bends the course of each toward its proper electrode, till the moment when, meeting with an unappropriated molecule of the opposite kind, it enters again into a more or less permanent union with it till it is again dissociated by another shock. Electrolysis, therefore, is a kind of diffusion assisted by electromotive force.

Another branch of molecular science is that which relates to the exchange of molecules between a liquid and a gas. It includes the theory of evaporation and condensation, in which the gas in question is the vapor of the liquid, and also the theory of the absorption of a gas by a liquid of a different substance. The researches of Dr. Andrews on the relations between the liquid and the gaseous state have shown us that, though the statements in our own elementary textbooks may be so neatly expressed that they appear almost self-evident, their true interpretation may involve some principle so profound that, till the right man has laid hold of it, no one ever suspects that any thing is left to be discovered.

These, then, are, some of the fields from which the data of molecular science are gathered. We may divide the ultimate results into three ranks, according to the completeness of our knowledge of them.