on the surface of charcoal-grains; the first layer of molecules must be consumed before the second can be reached, and so on. Hence the process, although very rapid, must take a sensible time. In the nitro-glycerine, on the other hand, the two sets of atoms, so far from being in different grains, are in one and the same molecule, and the internal combustion is essentially instantaneous. Now, this element of time will explain a great part of the difference in the effect of the two explosions, but a part is also due to the fact that nitro-glycerine yields fully nine hundred times its volume of gas, while with gunpowder the volume is only about three hundred times that of the solid grains. There is a further difference in favor of the nitro-glycerine in the amount of energy liberated, but this we will leave out of account, although it is worthy of notice that energy may be developed by internal molecular combustion as well as in the ordinary processes of burning.
"The conditions, then, are these: With gunpowder we have a volume of gas, which would normally occupy a space three hundred times as great as the grains used, liberated rapidly, but still in a perceptible interval. With nitro-glycerine a volume of gas, nine hundred times that of the liquid used, is set free, all but instantaneously. Now, in order to appreciate the difference of effect which would follow this difference of condition, you must remember that all our experiments are made in air, and that this air presses with an enormous weight on every surface. If a volume of gas is suddenly liberated, it must lift this whole weight, which, therefore, acts as so much tamping material. This weight, moreover, cannot be lifted without the expenditure of a large amount of work. Let us make a rough estimate of the amount in the case of nitro-glycerine. We will assume that in the experiment at Newport the quantity exploded yielded a cubic yard of gas. Had the air given way instead of the rock, the liberation of this volume of gas must have lifted the pressure on one square yard (about nine tons) one yard high, an amount of work which, using these large units, we will call nine yard-tons, or about sixty thousand foot-pounds. Moreover, this work must have been done during the excessively brief duration of the explosion, and, it being less work to split the rock, it was the rock that yielded, and not the atmosphere. Compare now, the case of gunpowder. The same weight of powder would yield only about one-third of the volume of gas, and would, therefore, raise the same weight to only one-third of the height; doing, therefore, but one-third of the amount of work, say twenty thousand foot-pounds. Moreover, the duration of the explosion being at least one hundred times longer than before, the work to be done in lifting the atmosphere during the same exceedingly short interval would be only 1⁄100 of twenty thousand foot-pounds, or two hundred foot-pounds, and, under these circumstances, you can conceive that it might be easier to lift the air than to break the rock.[1]. . . . .
- ↑ We here omit, for want of space, the beautiful explanation, afforded by the "New
