Page:Chance, love, and logic - philosophical essays (IA chancelovelogicp00peir 0).pdf/190

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the wall so often as they otherwise would, and the pressure will be less increased by compression.

When the kinetical theory of gases was first proposed by Daniel Bernoulli, in 1738, it rested only on the law of Boyle, and was therefore pure hypothesis. It was accordingly quite naturally and deservedly neglected. But, at present, the theory presents quite another aspect; for, not to speak of the considerable number of observed facts of different kinds with which it has been brought into relation, it is supported by the mechanical theory of heat. That bringing together bodies which attract one another, or separating bodies which repel one another, when sensible motion is not produced nor destroyed, is always accompanied by the evolution of heat, is little more than an induction. Now, it has been shown by experiment that, when a gas is allowed to expand without doing work, a very small amount of heat disappears. This proves that the particles of the gas attract one another slightly, and but very slightly. It follows that, when a gas is under pressure, what prevents it from collapsing is not any repulsion between the particles, since there is none. Now, there are only two modes of force known to us, force of position or attractions and repulsions, and force of motion. Since, therefore, it is not the force of position which gives a gas its expansive force, it must be the force of motion. In this point of view, the kinetical theory of gases appears as a deduction from the mechanical theory of heat. It is to be observed, however, that it supposes the same law of mechanics (that there are only those two modes of force) which holds in regard to bodies such as we can see and examine, to hold also for