Page:Elementary Principles in Statistical Mechanics (1902).djvu/165

From Wikisource
Jump to navigation Jump to search
This page has been proofread, but needs to be validated.
THROUGH LONG PERIODS OF TIME.
141

will all pass out of the given extension and all return within it. The whole of the given extension-in-phase is made up of parts of these two kinds. This does not exclude the possibility of phases on the boundaries of such parts, such that systems starting with those phases would leave the extension and never return. But in the supposed distribution of an ensemble of systems with a uniform density-in-phase, such systems would not constitute any assignable fraction of the whole number.

These distinctions may be illustrated by a very simple example. If we consider the motion of a rigid body of which one point is fixed, and which is subject to no forces, we find three cases. (1) The motion is periodic. (2) The system will never return to its original phase, but will return infinitely near to it. (3) The system will never return either exactly or approximately to its original phase. But if we consider any extension-in-phase, however small, a system leaving that extension will return to it except in the case called by Poinsot 'singular,' viz., when the motion is a rotation about an axis lying in one of two planes having a fixed position relative to the rigid body. But all such phases do not constitute any true extension-in-phase in the sense in which we have defined and used the term.[1]

In the same way it may be proved that the systems in a canonical ensemble which at a given instant are contained within any finite extension-in-phase will in general return to
  1. An ensemble of systems distributed in phase is a less simple and elementary conception than a single system. But by the consideration of suitable ensembles instead of single systems, we may get rid of the inconvenience of having to consider exceptions formed by particular cases of the integral equations of motion, these cases simply disappearing when the ensemble is substituted for the single system as a subject of study. This is especially true when the ensemble is distributed, as in the case called canonical, throughout an extension-in-phase. In a less degree it is true of the microcanonical ensemble, which does not occupy any extension-in-phase, (in the sense in which we have used the term,) although it is convenient to regard it as a limiting case with respect to ensembles which do, as we thus gain for the subject some part of the analytical simplicity which belongs to the theory of ensembles which occupy true extensions-in-phase.