Page:Experimental researches in chemistry and.djvu/244

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1827.]
On Labarraque's Disinfecting Soda Liquid.
229

chlorine should simultaneously be given off into the air; or what would take place, if the water were abstracted without the evolution of chlorine, I have not determined.

18. Notwithstanding the perfect manner in which the chlorine may be thus separated by crystallization and slow evaporation to dryness, yet it is certain that by quick evaporation a substance apparently quite dry may be obtained, which yet possesses strong bleaching power. In one experiment, where, of two equal portions, one had been evaporated in the course of twenty-four hours to dryness upon the warm part of a sand-bath, it, when compared with the former, had not lost more than one-third of its bleaching power.

19. With the desire of knowing what effect carbonic acid would have on Labarraque's fluid, and whether it possessed in a greater or smaller degree the power of ordinary acids to expel the chlorine, portions of the solution were put into two Woulfe's bottles, and a current of carbonic acid gas passed through them. The gas was obtained from sulphuric acid and whitening in a soda-water apparatus, and was well washed in water. The stream of gas brought away small portions of chlorine with it, but they were not sensible to the smell, and could only be detected by putting litmus paper into the current. An immense quantity of gas, equal to nearly 1300 times the volume of the fluid, was sent through; but yet very little chlorine was removed, and the bleaching powers of the fluid were but little diminished, though it no longer appeared alkaline to turmeric paper. Air was then passed through the solution in large quantity; it also removed chlorine, but apparently not quite so much as carbonic acid.

20. One other experiment was made upon the degree in which the carbonate of soda in Labarraque's liquor resisted decomposition by the chlorine, even at high temperature. Two equal portions of the fluid were taken, and one of them boiled rapidly for fifteen minutes; both were then acted upon by sulphuric acid, blowing and heat, as described (11), and the two were then tested by nitrate of silver, to ascertain the quantity of chlorine remaining: it was nearly three times as much in the boiled as in the unboiled portion; and by comparing this with the results before obtained (11), it will be seen, that after boiling for a quarter of an hour, not more than a twentieth