Page:Experimental researches in chemistry and.djvu/448

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1857.]
of Gold (and other Metals) to Light.
433

from ruby to blue, such as could be effected on loose ruby particles. Strong hydrochloric acid caused no change as long as the tissue held together; but as that became loose the gold flowed out into the acid in ruby-amethystine streams, finally changing to blue. Caustic potassa caused no change for days whilst the tissue kept together, but on mixing all up by pressure the loosened gold became at last blue. Strong nitric acid caused no change of colour until, by altering the tissue, the gold particles first flowed out in ruby and amethystine streams, and then were gradually changed to the condition of common aggregated gold. All these effects, and the actions on light, accord with the idea that the stain was simply due to diffused particles of finely-divided gold; and I am satisfied that all such stains upon the skin, or other organic matter, are of exactly the same nature.

As to the gold in ruby glass, I think a little consideration is sufficient to satisfy one that it is in the metallic condition. The action of heat tends to separate gold from its state of combination, and when so separated from the chloride, either upon the surface of glass, rock-crystal, topaz, or other inactive bodies, a ruby film of particles is frequently obtained. The sunlight and lens show that in ruby glass the gold is in separated and diffused particles. The parity of the gold glass, with the ruby-gold deflagrations and fluids described, is very great. These considerations, with the sufficiency of the assigned cause to produce the ruby tint, are strong reasons, in the absence of any to the contrary, to induce the belief that finely divided metallic gold is the source of the ruby colour.

When a pure, clean, stiff jelly is prepared, and mixed, whilst warm and fluid, with a little dilute chloride of gold, as if to prepare a ruby fluid, it gelatinizes when cold, and if left for two or three days may become a ruby jelly; sometimes, however, the gold in the jelly changes but little or changes to blue, or it may happen that it is reduced on the surface as a film, brilliant and metallic by reflected light, and blue-grey by transmitted light. I have not yet ascertained the circumstances determining one or the other state. If a trace of phosphorus in sulphide of carbon be added to the solution of gold in a dilute state, and some salt be added to the warm jelly, and the latter be then mixed gradually and with agitation with the gold