Page:Experimental researches in chemistry and.djvu/450

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1857.]
of Gold (and other Metals) to Light.
435

any length of time. It is perfectly neutral; gives no signs of dissolved gold by any of the tests of the metal; is not changed by sulphuretted hydrogen, gallic acid, pyrogallic acid, dilute caustic alkalies, or carbonated alkalies or lime-water; or by dilute sulphuric, hydrochloric or nitric acids, the actions being continued for fourteen days:—being boiled with zinc filings, it doe not change; and even when dilute sulphuric or hydrochloric acid is added to evolve nascent hydrogen, still the ruby character undergoes no alteration. Strong sulphuric, or nitric, or hydrochloric acid does not alter it whilst cold; but when warmed, the first causes the gold to separate as dark aggregated metallic particles, and the two latter gradually cause the change to amethyst and blue formerly described. Chlorine, or a mixture of hydrochloric and nitric acids, dissolves the gold, the ruby colour disappears, and the ordinary solution of gold is produced. In all these cases the ruby gold behaves exactly as metallic gold would do with the same agents, and quite unlike what would be expected from any possible combination of oxygen and gold.

In some of these jellies the ruby particles are so determinate as to give the brown reflexion by common observation; in others they are so line as to look like ruby solutions, unless a strong sunlight and a lens be employed; and the impression again arises, that gold may exist in particles so minute as to have little or no power of reflecting light. Ruby particles of extreme fineness, when present in small amount in water, appear to remain equally diffused for any length of time; if in larger amount, that which settles to the bottom will remain for weeks and months as a dense ruby fluid, but without coming together: both circumstances seem to imply an association of the particles of gold with envelopes of water. Many circumstances about the ruby jellies imply a like association with that animal substance, and many of the stains of gold upon organic substances probably include an affinity of the metal of the like kind. Relations of Gold (and other metals) to polarized Light. It has been already stated, that when a ray of common light passes through a piece of gold-leaf inclined to the ray, the light is polarized. When the angle between the leaf and the ray is small, about 15°, nearly all the light that passes is polarized;