between these two constituents of alum baking powder there is formed an equivalent quantity of sulfate of soda and hydroxid of alumina if the acid constituent be basic aluminium sulfate.
The quantity of residue left in the loaf if two teaspoonsful of baking powder be used is about 11 grams (165 grains).
Harmfulness of Baking Powder Residues.—The question of the harmfulness of the residues left by the various forms of baking powder is one which has been of much interest to the hygienist and physician. It is not claimed in any case that these residues are beneficial. The principal question which has been discussed is which of them is the least harmful. This is a question which it is not proper to enter into in this manual. It might, however, not be out of place to say that the use of chemical reagents for leavening bread is not as advisable as the use of the ordinary fermentation. It would be better, evidently, if all people used more yeast bread and less baking powder rolls. At the same time the utility and convenience of baking powder cannot be denied, and this is a factor which must be taken into consideration in the general discussion and final resolution of the question.
Character of Alum Residues.—Every one is agreed that the substance known as alum, namely, the sulfate of alumina in conjunction with another mineral or base, such as soda, potash, or ammonia, is not a desirable constituent of food products. In the manufacture of baking powders containing alum an effort is made to so balance the constituents that when the reaction is completed no undecomposed alum remains. If this condition is secured in every instance the materials which remain in the bread are not alum but the residues above mentioned, consisting of aluminium hydrate, and sulfates of soda, potash, or ammonia.
The residue of chief importance is the hydroxid or hydrate of alumina, which is the form in which the alumina itself should appear when a complete reaction like that defined above takes place. When the hydroxid of alumina is dried and especially when ignited it is converted into an oxid of alumina which is highly insoluble in water and only slightly soluble in a very dilute acid solution. The claim is made by the manufacturer of alum powders that the aluminium residue which is formed is insoluble in the digestive juices and therefore cannot produce any effect usually ascribed to the soluble salts of aluminium. It is important that the conditions which are found in the baking of a loaf are such as to produce this highly desirable result. The temperature of the interior of the loaf during baking does not rise much above that of boiling water, although the exterior temperature, which is sufficient to produce the browning of the crust, is very much above that temperature. It is evident that as long as any considerable proportion of water remains in the loaf it will be difficult to raise the interior of the loaf to the temperature just mentioned, and if this were done the caramelization would take place throughout the whole loaf. Unfortunately, from a scientific point of view
