alkaline sulphates, which have no visible action except on the barytic solution, and cause in it a heavy white precipitate, insoluble in nitric acid. From the chlorides of calcium and strontium, it is to be distinguished by evaporating the solution till it crystallizes. The crystals are known not to be chloride of calcium, because they are not deliquescent. The chloride of strontium (which resembles that of barium in many properties, but which must be carefully distinguished, as it is not poisonous), differs in the form of the crystals, which are delicate six-sided prisms, while those of the barytic salt are four-sided tables, often truncated on two opposite angles, sometimes on all four,—by its solubility in alcohol, which does not take up the chloride of barium,—and by its effect on the flame of alcohol, which it colours rose-red, while the barytic salts colour it yellow. The chloride of barium is known from other soluble barytic salts, by the action of nitrate of silver, which throws down a white precipitate.
Vegetable and animal fluids do not decompose the solution of chloride of barium, except by reason of the sulphates and carbonates which most of them contain in small quantities. But the action of its tests may be distinguished, although the salt has not undergone decomposition. In that case the most convenient method of analysis is to add a little nitric acid, which will dissolve any carbonate of baryta that may have been formed,—to filter and then throw down the whole baryta in the form of sulphate, by means of the sulphate of soda,—and to collect the precipitate, and calcine it with charcoal for half an hour in a platinum spoon or earthen crucible, according to the quantity. A sulphuret of baryta will thus be procured, which is to be dissolved out by boiling water, and decomposed after filtration by muriatic acid. A pure solution is thus easily obtained. Orfila has lately proposed a process more complex in its details, but the same in principle.[1]
Section II.—Of the Action of the Salts of Baryta, and the Symptoms they excite in Man.
The action of the barytic salts on the body is energetic. Like most metallic poisons, they seem to possess a twofold action,—one local and irritating, the other remote and indicated by narcotic symptoms. This narcotic action is more decided and invariable than in the instance of any of the metallic poisons hitherto noticed. Such at least is the result of the experiments of Sir B. Brodie,[2] which have since been amply confirmed by Professor Orfila[3] and Professor Gmelin.[4] Orfila found that when the chloride was injected into the veins of a dog in the dose of five grains only, death ensued in six minutes, and was preceded by convulsions, at first partial, but afterwards affecting the whole body. Sir B. Brodie found the same effects follow in twenty minutes, when ten grains were applied to a
