Page:Experimental researches in chemistry and.djvu/415

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400
On the Experimental Relations
[1857

untouched. The Arts do not seem to furnish any process which can instruct us as to this condition, for all the operations of polishing, burnishing, &c. applied to gold, silver and other metals, are just as much fitted to produce the required state under one view as under the other.

To return to gold: it is clear that that metal, reduced to small dimensions by mere mechanical means, can appear of two colours by transmitted light, whatever the cause of the difference may be. The occurrence of these two states may prepare one's mind for the other differences with respect to colour, and the action of the metallic particles on light, which have yet to be described.

Many leaves of gold, when examined by a lens and transmitted light, present the appearance of red parts; these parts are small, and often in curved lines, as if a fine hair had been there during the beating. At first I thought the gold was absolutely red in these parts, but am inclined to believe that in the greatest number of cases the tint is subjective, being the result of the contrast between the white light transmitted through bruised parts, and the green light of the neighbouring continuous parts. Nevertheless, some of these places, when seen in the microscope, appeared to have a red colour of their own, that is, to transmit a true red light. As I believe that gold in a certain state of division can transmit a ruby light, I am not prepared to say that gold-leaf may not, in some cases, where the effect of pressure in a particular direction has been removed, do the same.

Many of the prepared films of gold were so thin as to have their reflective power considerably reduced, and that in parts which, under the microscope and in other ways, appeared to be quite continuous: this agrees with the transmission of all the rays already mentioned, but it seems to imply that a certain thickness is necessary for full reflexion; therefore, that more than one particle in depth is concerned in the act, and that the division of gold into separate particles by processes to be described, may bring them within or under the degree necessary for ordinary reflexion.

As particles of pure gold will be found hereafter to adhere by contact, so the process of beating may be considered as one which tends to weld gold together in all directions, and