Page:Experimental researches in chemistry and.djvu/416

From Wikisource
Jump to navigation Jump to search
This page has been proofread, but needs to be validated.
1857.]
of Gold (and other Metals) to Light.
401

especially in that transverse to the blow,—a point favourable to continuity in that direction, both as it tends to preserve and even reproduce it.

If a polarized ray be received on an analyser so that no light passes, and a plate of annealed glass, either thick or thin, be interposed vertically across the ray, and no difference is observed you looking through the analyser, the image of the source of light does not appear; but if the plate be inclined until it makes an angle of from 30° to 45°, or thereabouts, with the ray, the light appears, provided the inclination of the glass is not in the plane of polarization or at right angles to it, the effect being a maximum if the inclination be in aplane making an angle of 45° with that of polarization. This effect, which is common to all uncrystallized transparent bodies, is also produced by leaf–gold, and is one of the best proofs of the true transparency of this metal according to the ordinary meaning of the term. In like manner, if a leaf of gold be held obliquely across an ordinary ray of light, it partly polarizes it, as Mr. De la Rue first pointed out to me. Here again the condition of true transparency is established, for it acts like a plate of glass or water or air. But the relations of gold and the metals in different conditions to polarized light shall be given altogether at the close of this paper.

Deflagsrations of Gold (and other metals)—heat—pressure, &c.

Gold wire deflagrated by explosions of a Leyden battery produces a divided condition, very different to that presented by gold leaves. Here the metal is separated into particles, and no pressure in any direction, either regular or irregular, has been exerted upon them in the act of division. When the deflagrations have been made near surfaces of glass, rock crystal, topaz, fluor-spar, card-board, &c., the particles as they are caught are kept separate from each other and in place, and generally those which remain in the line of the discharge have been heated by the passage of the electricity. The deposits consist of particles of various sizes, those at the outer parts of the result being too small to be recognized by the highest powers of the microscope. Beside making these deflagrations over different substances, as described above, I made them in different atmospheres, namely, in oxygen and hydrogen, to