oyster-shells, etc. In the true spirit of experiment he began by strongly heating his retorts (one of which was a musket barrel) to make sure that no air arose from them. It is not evident to me why he continued at this subject so long. He had no means of distinguishing one gas from another, and almost the only quality noted is a want of permanence, e.g. when the CO2 produced was dissolved by the water over which he collected it. Sir E. Thorpe[1] points out that Hales must have prepared hydrogen, carbonic acid, carbonic oxide, sulphur dioxide, marsh gas, etc. It may, I think, be said that Hales deserved the title usually given to Priestley, viz. "the father of pneumatic[2] chemistry."
Perhaps the most interesting experiment made by Hales is the heating of minium (red-lead) with the production of oxygen. It proves that he knew, as Boyle, Hooke and Mayow did before him, that a body gains weight in oxidation. Thus Hales remarks: "That the sulphurous and aereal particles of the fire are lodged in many of those bodies which it acts upon, and thereby considerably augments their weight, is very evident in Minium or Red Lead which is observed to increase in weight in undergoing the action of the fire. The acquired redness of the Minium indicating the addition of plenty of sulphur in the operation." He also speaks of the gas distilled from minium, and remarks "It was doubtless this quantity of air in the minium which burst the hermetically sealed glasses of the excellent Mr Boyle, when he heated the Minium contained in them by a burning glass" (p. 287).
This was the method also used by Priestley in his celebrated experiment of heating red-lead in hydrogen; whereby the metallic lead reappears and the hydrogen disappears by combining with the oxygen set free. This was expressed in the language of the day as the reconstruction of metallic lead by the addition of phlogiston (the hydrogen) to the calx of lead (minium). Thorpe points out the magnitude of the discovery that Priestley missed, and it may be said that Hales too was on
- ↑ History of Chemistry, 1909, I. p. 69.
- ↑ Hales made use of a rough pneumatic trough, the invention of which is usually ascribed to Priestley (Thorpe's History of Chemistry, I. p. 79).
