Page:Popular Science Monthly Volume 9.djvu/588

From Wikisource
Jump to navigation Jump to search
This page has been validated.
562
THE POPULAR SCIENCE MONTHLY.

The importance attached to the refutation of this theory may be judged of from the circumstance that, after the early experiments of Lavoisier on the composition and decomposition of water had been successfully repeated by a committee of the French Academy in 1790, a congratulatory meeting was held in Paris, at which Madame Lavoisier, attired as a priestess, burned on an altar Stahl's celebrated "Fundamenta Chemiæ Dogmaticæ et Experimentalis," solemn music playing a requiem the while. And the sort of estimation in which the Stahlian doctrines have since been held by chemists is fairly illustrated by a criticism of Sir J. Herschel, who, speaking of the phlogistic theory of chemistry, says that it "impeded the progress of the science, as far as a science of experiment can be impeded by a false theory, . . . . by involving the subject in a mist of visionary and hypothetical causes in place of the true acting principles." Possibly, however, this much-abused theory may yet prove to contain an element of permanent vitality and truth; anyhow the study of this earliest and most enduring of chemical theories can never be wholly devoid of interest to chemists.

To appreciate the merit of the phlogistic theory it is necessary to bear in mind the period of its announcement. Its originator, Beccher, was born in 1625, and died a middle-aged but worn-out man in 1682, a few years before the publication of the "Principia." His more fortunate disciple, Stahl, who was born in 1660, and died in 1734, in his seventy-fifth year, though afforded a possibility of knowing, seems equally with Beccher to have remained throughout his long career indifferent to the Newtonian principle that the weight of a body is proportionate to its quantity of matter—that loss of weight implies of necessity abstraction of matter, and increase of weight addition of matter. Whether or not the founders of the phlogistic theory conceived that change of matter in the way of kind might, equally with its change in point of quantity, be associated with an alteration in weight—and it must not be forgotten what pains Newton thought it necessary to take in order to show the contrary—certain it is, they attached very little importance to the changes of weight manifested by bodies undergoing the metamorphosis of combustion. It might be that when combustible charcoal was burned the weight of incombustible residue was less than the original weight of charcoal it might be that when combustible lead was burned the weight of incombustible residue was greater than the original weight of metal—this was far too trifling an unlikeness to stand in the way of the paramount likeness presented by the two bodies. For the lead and charcoal had the common property of manifesting the wonderful energy of fire; they could alike suffer a loss of light and heat—that is, of phlogiston—by the deprivation of which they were alike changed into greater or less weights of inert incombustible residue.

And not only were these primitive students of the philosophy of