- tains carbonate of potash; because the latter attracts much moisture
when kept for some time.—If the quantity operated on is large it should be mixed with the flux before being introduced into the tube; if it is small, it may be dropped into the tube and covered with charcoal. The materials are to be introduced along a little triangular gutter of stiff paper, if the tube is large; but with a small tube it is preferable to use the little glass funnel represented in Fig. 2, to which a wire is previously fitted, for pushing the matter down when it adheres. The material should not be closely impacted. Heat is best applied with the spirit-lamp, first to the upper part of the material, with a small flame, and then to the bottom of the tube, the flame being previously enlarged. A little water, disengaged in the first instance, should be removed with a roll of filtering paper, before a sufficient heat is applied to sublime the metal. As soon as the dark crust begins to form, the tube should be held steady in the same part of the flame. With these precautions a well defined crust will be procured with facility.
The characters of the crust have been mentioned already under the head of fly-powder (p. 199). They are distinct even in crusts weighing only a 300th of a grain. A crust of this weight, a tenth of an inch broad and four times as long, may show characteristically all the physical characters of an arsenical sublimate a hundred times larger.
The fallacies to which the test has been supposed to be liable (excluding at present that part of it which consists in the oxidation of the metal, and which renders it quite unimpeachable), are the following.— Dr. Paris says he has known an instance where a person, "by no means deficient in chemical address, mistook for it a deposit of charcoal,[1] and I have known the same mistake happen in the hands of one of my pupils, a beginner in the study of medico-legal chemistry. The outer surface of a charcoal crust may be mistaken for arsenic by a careless person; but with ordinary care it is quite impossible to err if the inner surface be examined, for that of charcoal is brown, powdery, and perfectly dull.—It has been suggested to me and has been stated in print,[2] that the preparations of antimony yield by reduction a sublimate resembling closely an arsenical crust. But in consequence of repeated trials I am certain that no preparation of antimony, reduced either by charcoal or the black-flux with the fullest red heat of the blowpipe will yield any metallic sublimate; and the same facts were observed by the late Dr. Turner.—It has even been said by Mr. Donovan that the action of the flux on glass which contains lead causes a stain similar to an arsenical crust.[3] If it be meant by this observation, that the lead contained in the glass usually gives that part of the tube which contains the flux a glimmering appearance and impairs its transparency, the author is correct: but it is impossible that a sublimate can be so formed.—Dr. Mitchell of Philadelphia in an elaborate paper on the process of re-*
