The hypothesis of Grouhuss and Davy was attacked in 1825 by Anguste De La Rive[1] (b. 1801, d. 1873) of Geneva, on the ground of its failure to explain what happens when different liquids are placed in series in the circuit. If, for example, a solution of zinc sulphate is placed in one compartment, and water in another, and if the positive pole is placed in the solution of zinc sulphate, and the negative pole in the water, De La Rive found that oxide of zinc is developed round the latter; although decomposition and recomposition of zine sulphate could not take place in the water, which contained none of it. Accordingly, he supposed the constituents of the decomposed liquid to be bodily transported across the liquids, in close union with the moving electricity. In the electrolysis of water, one current of electrified hydrogen was supposed to leave the positive pole, and become decomposed into hydrogen and electricity at the negative pole, the hydrogen being there liberated as a gas. Another current in the same way carried electrified oxygen from the negative to the positive pole. In this scheme the chain of successive decompositions imagined by Grothuss does not take place, the only molecules decomposed being those adjacent to the poles.
The appearance of the products of decomposition at the separate poles could be explained either in Grothuss' fashion by assuming dissociations throughout the mass of liquid, or in De La Rive's by supposing particular dissociated atoms to travel considerable distances. Perhaps & preconceived idea of economy in Nature deterred the workers of that time from accepting the two assumptions together, when either of them separately would meet the case. Yet it is to this apparent redundancy that later researches have pointed as the truth. Nature is what she is, and not what we would make her,
De La Rive was one of the most thoroughgoing opponents of Volta's contact theory of the pile; even in the case when two metals are in contact in air only, without the intervention
- ↑ Anuales de Chimie, xxvii, 190.
