Page:Experimental researches in chemistry and.djvu/187

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172
On some new Products
[1825.

In the same way some of the more fixed essential oils may be used, as dry oil of turpentine; and even a portion of the condensed liquor itself as that part which requires a temperature of 220° or 230° for its ebullition; care being taken to estimate the expansion of the gas by the vapour of the liquid, which may readily be done by a known portion of common air preserved over the liquid as a standard.

With reference to the proportions of the different substances in the liquid as obtained by condensation of oil-gas, it is extremely difficult to obtain anything like precise results, in consequence of the immense number of rectifications required to separate the more volatile from the less volatile portions; but the following Table will furnish an approximation. It contains the loss of 100 parts by weight of the original fluid by evaporation in a flask, for every 10° in elevation of temperature, the substance being retained in a state of ebullition.

100 parts at 58°   parts differenes.
had lost at 70 . . . 1.1
  1.9
  80 . . . 3.0
  2.2
  90 . . . 5.2
  2.5
  100 . . . 7.7
  2.4
  110 . . . 10.1
  3.1
  120 . . . 13.2
  2.9
  130 . . . 16.1
  3.2
  140 . . . 19.3
  3.1
  150 . . . 22.4
  3.2
  160 . . . 25.6
  3.4
  170 . . . 29.0
  15.7
  180 . . . 447. 4
  23.4
  190 . . . 68.1
  16.1
  200 . . . 84.2
  7.4
  210 . . . 91.6
  3.7
  220 . . . 95.3
  1.3
  230 . . . 96.6

The residue, 3.4 parts, was dissipated before 250° with slight decomposition. The third column expresses the quantity volatilized between each 10°, and indicates the existence of what has been described as bicarburet of hydrogen in considerable quantity.