Page:Experimental researches in chemistry and.djvu/253

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238
On the Manufacture of Optical Glass.
[1829.

most injurious in its effect. It is not an improvement only beyond what is ordinarily done in this respect that is required, but absolute perfection, a homogeneity equal to that of pure water. In the two kinds of glass required to render a telescope achromatic, namely, crown or plate glass, and flint glass, it is the latter which is obtained perfect with the greatest difficulty, and to which therefore the greatest attention has been paid. The reason of this will be evident, if the general composition of the two glasses be taken into account. The required difference between them in refractive and dispersive power is found to be at command, by attention to composition; and it has been also ascertained, that crown and plate glass answer exceedingly well for the one variety, and flint glass for the other. Crown glass consists of silica, lime, oxide of iron, sometimes a little alkali, and small quantities of other matters: these substances are not very different in their refractive powers, and when fused do not produce very strong streaks, even though a little difference in the composition of different parts of the glass may exist. The glass also is not a very powerful Huxing agent upon the crucible in which it is melted; so that although it is in contact with it in a fluid and heated state for many hours, it does not dissolve much from it; and what it does dissolve having a refractive power little different from that of the glass itself, proportionately less harm is occasioned. Again: the specific gravity of the different materials used- is not very different; so that the mixing agencies which affect the contents of the pot,—such as the ascent of bubbles, the ascending and descending currents from difference of temperature,—are more energetically exerted, and the whole mass approaches nearer to uniformity in a given time, or acquires it sooner than would happen were greater differences to exist.

6. With plate glass the same circumstances hold nearly in an equal degree. This substance is composed of silica and alkali essentially, other elements being only in small quantities. Its action upon the crucible is greater than crown glass, but then it has a second application of heat in such circumstances as are calculated to give a very uniform temperature to the contents of a whole pot, and it is delivered into its final form in the manner least likely to cause mixture of the different parts.

7. With flint glass many circumstances are altogether differ-