Page:Experimental researches in chemistry and.djvu/281

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266
On the Manufacture of Optical Glass.
[1829.

equal time. The specific gravities of each after the experiments were as follows:—

Highest heat 5.4206 5.4211 5.4203 Mean sp.gr 5.42066
Intermediate heat 5.4253 5.4242 5.4255 Mean sp.gr. 5.42500
Least heat 5.4258 5.4262 5.4235 Mean sp.gr. 5.42516
Original glass 5.4247 5.4261   Mean sp.gr. 5.42540

72. Here, notwithstanding the irregularities between the similar experiments, there seems, from the comparison of the mean specific gravities, to be a gradual though minute diminution of density, as the glasses have been more powerfully heated; and I found also, that when glass was so well stirred as to leave no doubt that it was thoroughly well mixed, yet being left in the furnace at a high temperature for eight or nine hours, it contained striæ.

73. On the other hand, first to render the glass perfectly free from bubbles and clear, and then to stir out the irregularities of composition, I have not found to be a practicable process; because the stirring, in the manner in which I have yet performed it, tends to introduce bubbles into the glass; and though these are small, still they are objectionable. Hence a mixed process has been adopted, which, as I have before stated, is subject to correction from future experiments. To render the process as far as it has been carried sufficiently intelligible to others, I will first describe the circumstances connected with stirring, and their influence upon strim; and afterwards, the plans adopted for the dispersion of bubbles.

74. It is not a small degree of stirring and agitation which is sufficient to make a fluid of mixed materials homogeneous; especially when the mixture is not exceedingly fluid, but has, like tar or syrup, a considerable degree of tenacity. An idea of the extent to which it must be carried, and of the general nature of striaæ in fluids, may be gained by taking a glass full of clear saturated syrup, made from white sugar, putting a few drops of water into it, and stirring the whole together. It may then be remarked how slow the striæ are in disappearing; and when they are apparently destroyed, if the whole be left for some hours, it will frequently happen that a separation will take place into a lower heavy, and a superincumbent light portion, which, when stirred together again, produce strim. In the glass, the stirring must be in the utmost degree