Page:Experimental researches in chemistry and.djvu/286

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1829.]
On the Manufacture of Optical Glass.
271

stirring. This method has the advantage of bringing the assisting substance into contact with the glass when the latter is highly disposed to throw off its adhering gaseous matter, and also allow of thorough mixture; but it also causes the addition of fresh glass after the concoction of the materials has been proceeding for many hours; and it likewise occasions the introduction of many bubbles formed by the air in the inter stices of the powder.

86. On other occasions the prepared mixture of platinum and glass has been introduced into the tray at the period when it was charged with the due quantity of rough glass, and before the application of fire. Particular attention was then paid to its general diffusion throughout the charge, and on these occasions its action commenced the moment the glass in contact with it was fluid. I am inclined to believe the latter will ultimately prove the better method of proceeding, both for the greater length of time during which the platinum can act, and for the facility and convenience of its introduction.

87. In either mode of appliance the platinum has been found highly serviceable; and in every case since its use, where stirring has not been necessary, the resulting glass has proved to be perfectly free from bubbles.

88. As already mentioned, the best periods for stirring and repose have not been finally determined. Stirring introduces bubbles, and therefore should, if possible, be avoided towards the conclusion of the experiment. Rest, or at least that condition in which there is no other motion than what is due to the currents produced by slight differences of temperature, causes strife even after very careful mixture (71. 72), and is therefore equally to be feared; and' whatever other variations may have been adopted, I have always found it important to apply a careful concluding stirring. The following may be considered as the order of an experiment. If the spongy platinum has not been introduced into the tray with the rough glass, then about the sixth hour after lighting the fire it is added in the manner already directed (85), and the glass well stirred (76). At about the twelfth hour the stirrings are recommenced, for the purpose of making the mixture perfect, and are repeated every 20 or 30 minutes, according to the fusibility of the glass and the state of the heat (60), for eight or nine times. The glass is