Page:Experimental researches in chemistry and.djvu/388

From Wikisource
Jump to navigation Jump to search
This page has been proofread, but needs to be validated.
1850.]
On Ice and Freezing Water.
373

into this country under the name of the Wenham Lake ice (though it is chiefly supplied from Norway) may be regarded as one of the purest natural substances. Mr. Faraday first showed how entirely colouring matter, salts and alkalies are expelled in freezing[1]. A solution of sulphate of indigo, diluted sulphuric acid, and diluted ammonia were partially frozen in glass test-tubes: as soon as the operation had been carried on long enough to produce an icy lining of each tube, the unfrozen liquid was poured out and the ice dislodged. This ice was found in every instance perfectly colourless, and, when dissolved, perfectly free from acid or alkali, although the unfrozen liquid exhibited in the first experiment a more intense blue colour, in the second a stronger acid, and in the third a more powerful alkaline reaction than the liquor which was put into the freezing mixture. Mr. Faraday also devised a method for making this ice perfectly clear and transparent as well as colourless. By continually stirring the liquid, while freezing, with a feather, he brushed away globules of air as fast as they were dislodged from the freezing fluid, and thus prevented their becoming imbedded in the ice. Having noticed the rapidity with which water absorbs air as soon as it is thawed, Mr. Faraday called attention to the importance of this natural arrangement to aquatic plants and animals, to whose life air is as indispensable as to those which live on land. Mr. Faraday then referred to Mr. Donny's discovery, that water, when deprived of air, does not boil till it reaches the temperature of 270°, and that at that degree of heat it explodes. He mentioned that he suggested to Mr. Donny that ice when placed in oil (so as to prevent its receiving any air from the atmosphere on thawing) would probably explode on reaching a sufficient temperature. This experiment had been successfully tried by Mr. Donny, and was as successfully repeated on this occasion. Mr. Faraday then invited attention to the extraordinary property of ice in solidifying water which is in contact with it. Two pieces of moist ice will consolidate into one. Hence the property of damp snow to become compacted into a snowball—an effect which cannot be produced on dry, hard-frozen snow. Mr. Faraday suggested, and illustrated by a diagram, that a film of water must possess the property of freezing when placed between two

  1. See ice from solution of chlorine, p. 82.