Page:Experimental researches in chemistry and.djvu/53

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88
On two new Compounds
[1820.

has scarcely any taste. Its odour is aromatic, and approaching to that of camphor. Its specific gravity is as nearly as possible 2. Its refractive power is high, being above that of flint glass (1.5767). It is very friable, easily breaking down under pressure; and when scratched has much of the feel and appearance of white sugar. It does not conduct electricity.

The crystals obtained by sublimation and from solutions of the substance in alcohol and æther, are dendritical, prismatic, or in plates; the varieties of form, which are very interesting, are easily ascertained, and result from a primitive octahedron.

It volatilizes slowly at common temperatures, and passes, in the manner of camphor, towards the light. If warmed, it rises more rapidly, and then forms line crystals: when the temperature is further raised, it fuses at 320° Fahr. and boils at 360° under atmospheric pressure. When condensed again from these rapid sublimation's, it concretes in the upper part of the tube or vessel containing it, in so transparent and colourless a state, that it is difficult, except from its high refractive power, to perceive where it is lodged. As the crust it forms becomes thicker, it splits, and cracks like sublimed camphor; and in a few minutes after it is cold, is white, and nearly opake. If the heat be raised still higher, as when the substance is passed through a red-hot tube, it is decomposed, chlorine is evolved, and another chloride of carbon, which condenses into a fluid, is obtained. This shall be described presently.

It is not readily combustible; when held in the dame of a spirit-lamp, it burns with a red flame, emitting much smoke and acid fumes; but when removed from the lamp, combustion ceases. In the combustion that does take place in the lamp, the hydrogen of the alcohol, by combining with the chlorine of the compound, performs the most important part; nevertheless, when the substance is heated red in an atmosphere of pure oxygen, it sometimes burns with a brilliant light.

It is not soluble in water at common temperatures, or only in very small quantity. When a drop or two of the alcoholic solution is poured into a large quantity of water, it renders it turbid from the deposition of the substance. It does not appear that hot water dissolves more of it than cold water.

It dissolves in alcohol with facility, and in much greater quantity with heat than without. A saturated hot solution crystal-