Page:Experimental researches in chemistry and.djvu/85

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70
On the Alloys of Steel.
[1822.

cible, and placed in the furnace, to attend to it while there, and to suffer it to remain for some considerable time in a state of thin fusion, previous to its being poured out into the mould. The cast ingot was next, under the same superintendence, taken to the tilting mill, where it was forged into bars of a convenient size, at a temperature not higher than just to render the metal sufficiently malleable under the tilt hammer. When returned to us, it was subjected to examination both mechanical and chemical, aswell as compared with the similar products of the laboratory. From the external appearance, as well as from the texture of the part when broken by the blow of the hammer, we were able to form a tolerably correct judgement as to its general merits; the hardness, toughness, and other properties were further proved by severe trials, after being fashioned into some instrument or tool, and properly hardened and tempered.

It would prove tedious to enter into a detail of experiments made in the Royal Institution; a brief notice of them will at present be sufficient. After making imitations of various specimens of meteoric iron, by fusing together pure iron and nickel, in proportions of 3 to 10 per cent., we attempted making an alloy of steel with silver, but failed, owing to a superabundance of the latter metal; it was found, after very many trial, that only the 1/500 th part of silver would combine with steel, and when more was used a part of the silver was found in the form of metallic dew, lining the top and sides of the crucible: the fused button itself was a mere mechanical mixture of the two metals, globules of silver being pressed out of the mass by contraction in cooling, and more of these globules being forced out by the hammer in forging; and further, when the forged piece was examined, by dissecting it with diluted sulphuric acid, threads or fibres of silver were seen mixed with the steel, having something of the appearance of steel and platinum when united by welding: but when the proportion of silver was only 1500 th part, neither dew, globules, nor fibres appeared, the metals being in a state of perfect chemical combination, and the silver could only be detected by a delicate chemical test.

With platinum and rhodium, steel combines in every proportion; and this appears also to be the case with iridium and osmium: from 1 to 80 per cent. of platinum was perfectly