which ones are present or in what proportions. This example is also true for dusts, as was discussed previously for silica, or for metals which may exist in trace quantities.
In choosing bulk samples, the end goal must be considered: qualitative and/or quantitative analysis. In the case of a painting operation, it is preferred to have the bulk samples separated by contaminants of interest, i.e., solvent fraction separate from the pigment fraction. This allows the laboratory to analyze the different portions of the paints without having to go through a lengthy separation process. In general, the cleaner the bulk, the easier it will be for the laboratory to conduct the analysis. In many cases, the industrial hygienist is interested in a "dirty" bulk. Any information that can be given to the laboratory on what may or may not be present will help speed up the analysis. Advance consultation with the laboratory is desirable.
In choosing bulk dust samples, the sample should be representative of the airborne dust to which the workers are being exposed. Usually this is a settled dust sample collected from rafters or near the workers' job site. In other cases, a process dust sample is chosen to determine the composition of the material before it is airborne. In cases where the choice is not clear, do not follow the adage that "more is better." Bulk samples should be limited in number to optimize the laboratory's time. A good approach, when in doubt as to what bulks are needed, is to collect several but to allow the laboratory to analyze only those needed to answer questions as they arise.
When shipping bulks, care must be taken to preserve the integrity of the samples and to follow established Department of Transportation (DOT) shipping regulations. Only 5 to 10 mL of the liquid or solid is needed, so keep bulk sample sizes small. In general, leak-proof glass containers are best since they will not react with most chemicals; however, polyethylene containers can be used in the majority of cases. A convenient container is a 20-mL scintillation vial with PTFE-lined cap. Specific chemicals for which polyethylene containers should not be used include aromatic compounds, chlorinated hydrocarbons and strong acids. The lids of the containers should be sealed with shrink bands or tape for further assurance against leakage. These containers should be labeled as required by DOT under their regulations, 49 CFR Part 171-177. For most materials classified as "Flammable" or "Poisonous," amounts up to 1 quart can be shipped by any carrier. Most bulk dusts are not covered by DOT regulations. Specific restrictions and labeling requirements should be checked prior to shipping any samples.
In the case of volatile bulk samples (and some air samples), consideration should be given to shipping the samples on dry ice or with bagged refrigerant (e.g., "blue ice"). Do not ship volatiles together with air samples. Again, check with the carrier you plan to use as there may be restrictions on the amount of dry ice they will accept in a package (usually 5 pounds or less is acceptable). Specific labels are usually required when dry ice is used.
4. BLANKS
Certain numbers of blanks are required by the analytical laboratory for each set of samples to be analyzed. The specific method being used should be consulted concerning the number and type of blanks required. There are two types of sampler blanks: field and media blanks.
