first place determining the atomic weight of the metal. It has not yet been possible to carry out this research on account of the difficulties of a chemical nature already mentioned.
If polonium were proved to be a new element, it would be no less true that it cannot exist indefinitely in a strongly radio-active condition, at least when extracted from the ore. There are therefore two aspects of the question:—First, whether the activity of polonium is entirely induced by the proximity of substances themselves radio-active, in which case polonium would possess the faculty of acquiring atomic activity permanently, a faculty which does not appear to belong to any substance whatever; second, whether the activity of polonium is an inherent property, which is spontaneously destroyed under certain conditions, and persists under certain other conditions, such as those which exist in the ore. The phenomenon of atomic activity induced by contact is still so little understood, that we lack the ground on which to formulate any opinion on the matter.
(Note.—A work has recently appeared on polonium by M. Marckwald. He plunges a small rod of pure bismuth into a hydrochloric acid solution of the bismuth extracted from the pitchblende residue. After some time the rod becomes coated with a very active deposit, and the solution now contains only inactive bismuth. M. Marckwald also obtains a very active deposit by adding tin chloride to a hydrochloric acid solution of radio-active bismuth. From this he concludes that the active element is allied to tellurium, and gives it the name of radiotellurium. This active substance of M. Marckwald seems identical with polonium, from its behaviour, and from the easily absorbed rays it emits. The choice of a new name for this substance is futile in the present state of the question).
Preparation of the Pure Chloride of Radium.
The method by which I extracted pure radium chloride from barium chloride containing radium consists in first subjecting the mixture of the chlorides to fractional crystallisation in pure water, then in water to which hydrochloric acid has been added. The difference in solubility of the two chlorides is thus made use of, that of radium being less soluble than that of barium.
At the beginning of the fractionation, pure distilled water is used. The chloride is dissolved, and the solution raised to boiling-point, and allowed to crystallise by cooling in a
