Page:Radio-active substances.djvu/84

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76
mdme. curie's thesis:

duces induced radio-activity. The solution, however, of the same salt produces much more intense phenomena of induced radio-activity. With a solid salt the radio-active energy accumulates in the salt, and is dissipated chiefly by radiation. On the other hand, when the salt has been for several days in aqueous solution, the radio-active energy is divided between the salt and the water, and if separated by distillation the water carries with it a large portion of the activity, and the solid salt is much less active (ten or fifteen times) than before solution. Afterwards the solid salt gradually regains its original activity.

The preceding theory may be yet further defined by supposing the radio-activity of radium itself to be produced through the medium of the radio-active energy emitted in the form of an emanation.

Each atom of radium may be considered as a constant and continuous source of emanation. At the same moment that this form of energy is produced, it undergoes a progressive transformation into radio-active energy of the Becquerel radiation. The velocity of this transformation is proportional to the quantity of the emanation accumulated.

When a radium solution is placed within an enclosure, the emanation is able to expand into the enclosure and to spread out over the walls. Here it is, therefore, that it is transformed into a radiation, the solution giving off but few Becquerel rays; the radiation is, in some sort, externalised. On the other hand, with solid radium, the emanation not being able to escape readily, accumulates, and is transformed into the Becquerel radiation on the spot; this radiation therefore acquires a higher value.

If this theory of radio-activity were general, we should have to say that all radio-active bodies give rise to an emanation. Now this emission has been confirmed in the case of radium, thorium, and actinium; with the latter in particular the emission is enormous, even in the solid state. Uranium and polonium do not seem to emit any emanation, though they generate Becquerel rays. These bodies produce no induced radio-activity in an enclosed space, as do the radio-active bodies mentioned before. This fact is not in absolute contradiction to the preceding theory. If uranium and polonium were to emit emanations which become destroyed with very great rapidity, it would be very difficult to observe the carriage of such emanations by the air and the effects of induced radio-activity produced by them upon neighbouring bodies. Such a hypothesis is not improbable, since the times required for certain quantities of