behaviour, for it is quite probable that the active material in each case may exist only in minute quantity in the matter under examination, and, under such conditions, a direct chemical examination in the first place is of little value.
Recent work of Hofmann and Zerban and of Baskerville, however, certainly tends to show that the element thorium is itself non-radio-active, and that the radio-activity observed in ordinary thorium compounds is due to the admixture with it of an unknown radio-active element. Hofmann and Zerban[1] made a systematic examination of the radio-activity of thorium obtained from different mineral sources. They found generally that thorium, obtained from minerals containing a large percentage of uranium, were more active than those obtained from minerals nearly free from uranium. This indicates that the radio-activity observed in thorium may possibly be due to a transformation product of uranium which is closely allied chemically to thorium and is always separated with it. A small quantity of thorium obtained from the mineral gadolinite was found by Hofmann to be almost inactive, whether tested by the electric or by the photographic method. Later Baskerville and Zerban[2] found that thorium obtained from a Brazilian mineral was practically devoid of activity.
In this connection the recent work of Baskerville on the complexity of ordinary thorium is of interest. By special chemical methods, he succeeded in separating two new and distinct substances from thorium, which he has named carolinium and berzelium. Both of these substances are strongly radio-active, and it thus seems probable that the active constituent observed in ordinary thorium may be due to one of these elements.
If, as we have suggested, thorium itself is not active, it is certainly a matter of surprise that ordinary commercial thorium and the purest chemical preparations show about the same activity. Such a result indicates that the methods of purification have not removed any of the radio-active constituent originally present.
Whatever the radio-active constituent in thorium may ultimately prove to be, it is undoubtedly not radium nor actinium nor any of the known radio-active substances.
