Page:Reflections on the Motive Power of Heat.djvu/110

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88
MOTIVE POWER OF HEAT.

Since the difference between the two capacities for heat is constant, if one increases in arithmetical progression the other should follow a similar progression: thus one law is applicable to specific heats at constant pressure.

We have tacitly assumed the increase of specific heat with that of volume. This increase is indicated by the experiments of MM. Delaroche and Bérard: in fact these physicists have found 0.967 for the specific heat of air under the pressure of


    the ratio between the specific heat at constant pressure and the specific heat at constant volume varies very little with the density of the gas. According to what we have just seen, the difference should remain constant, and not the ratio. As, further, the specific heat of gases for a given weight varies very little with the density, it is evident that the ratio itself experiences but slight changes.

    The ratio between the specific heat of atmospheric air at constant pressure and at constant volume is, according to MM. Gay-Lussac and Welter, 1.3748, a number almost constant for all pressures, and even for all temperatures. We have come, through other considerations, to the number = 1.44, which differs from the former , and we have used this number to prepare a table of the specific heats of gases at constant volume. So we need not regard this table as very exact, any more than the table given on p. 89. These tables are mainly intended to demonstrate the laws governing specific heats of aeriform fluids.