Page:Reflections on the Motive Power of Heat.djvu/200

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176
THOMSON ON CARNOT'S

Note on the curves described in Clapeyron's graphical method of exhibiting Carnot's Theory of the Steam-Engine.

39. At any instant when the temperature of the water and vapor is t, during the fourth operation (see above, § 16, and suppose, for the sake of simplicity, that at the beginning of the first and at the end of the fourth operation the piston is absolutely in contact with the surface of the water), the latent heat of the vapor must be precisely equal to the amount of heat that would be necessary to raise the temperature of the whole mass, if in the liquid state, from t to S.[1] Hence, if v' denote the volume of the vapor, c the mean capacity for heat of a pound of water between the temperatures S

  1. For at the end of the fourth operation the whole mass is liquid, and at the temperature S. Now, this state might be arrived at by first compressing the vapor into water at the temperature t, and then raising the temperature of the liquid to S; and however this state may be arrived at, there cannot, on the whole, be any heat added to or subtracted from the contents of the cylinder, since, during the fourth operation, there is neither gain nor loss of heat. This reasoning is, of course, founded on Carnot's fundamental principle, which is tacitly assumed in the commonly-received ideas connected with "Watt's law," the "latent heat of steam," and "the total heat of steam."