Page:Reflections on the Motive Power of Heat.djvu/78

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56
MOTIVE POWER OF HEAT.

soon give a second more rigorous demonstration of this theory. This should be considered only as an approximation. (See page 59.)

We have a right to ask, in regard to the proposition just enunciated, the following questions: What is the sense of the word maximum here? By what sign can it be known that this maximum is attained? By what sign can it be known whether the steam is employed to greatest possible advantage in the production of motive power?

Since every re-establishment of equilibrium in the caloric may be the cause of the production of motive power, every re-establishment of equilibrium which shall be accomplished without production of this power should be considered as an actual loss. Now, very little reflection would show that all change of temperature which is not due to a change of volume of the bodies can be only a useless re-establishment of equilibrium in the caloric.[1] The necessary condition of the maximum is, then, that

  1. We assume here no chemical action between the bodies employed to realize the motive power of heat. The chemical action which takes place in the furnace is, in some sort, a preliminary action,—an operation destined not to produce immediately motive power, but to destroy the equilibrium of the caloric, to produce a difference of temperature which may finally give rise to motion.