Page:The Liquefaction of Gases.djvu/42

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38
Faraday.

obtained depended more upon depression of temperature than on the pressure which I could employ in these tubes, I endeavoured to obtain a still greater degree of cold. There are, in fact, some results producible by cold which no pressure may be able to effect. Thus, solidification has not as yet been conferred on a fluid by any degree of pressure. Again, that beautiful condition which Cagniard de la Tour has made known, and which comes on with liquids at a certain heat, may have its point of temperature for some of the bodies to be experimented with, as oxygen, hydrogen, nitrogen, &c., below that belonging to the bath of carbonic acid and ether; and, in that case, no pressure which any apparatus could bear would be able to bring them into the liquid or solid state.

To procure this lower degree of cold, the bath of carbonic acid and ether was put into an air-pump, and the air and gaseous carbonic acid rapidly removed. In this way the temperature fell so low, that the vapour of carbonic acid given off by the bath, instead of having a pressure of one atmosphere, had only a pressure of 124th of an atmosphere, or 1.2 inch of mercury; for the air-pump barometer could be kept at 28.2 inches when the ordinary barometer was at 29.4. At this low temperature the carbonic acid mixed with the ether was not more volatile than water at the temperature of 86°, or alcohol at ordinary temperatures.

In order to obtain some idea of this temperature, I had an alcohol thermometer made, of which the graduation was carried below 32° Fahr., by degrees equal in capacity to those between 32° and 212°. When this thermometer was put into the bath of carbonic acid and ether surrounded by the air, but covered over with paper, it gave the temperature of 106° below 0°. When it was introduced into the bath under the air-pump, it sank to the