Page:The Liquefaction of Gases.djvu/52

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48
Faraday.

a table of pressures in atmospheres of 30 inches mercury, of which the marked results are from many observations, the others are interpolated. They differ considerably from the results obtained by Bunsen,[1] but agree with my first and only result.

Fahr.
°
Atmospheres. Fahr.
°
Atmospheres. Fahr.
°
Atmospheres.
0 0.725 40 1.78 76 .8 3.50
10 0.92  46 .5 2.00 85 4.00
 √ 14 1.00   √ 48 2.06  √ 90 4.35
 √ 19 1.12   √ 56 2.42 93 4.50
 √ 23 1.23  58 2.50 98 5.00
 √ 26 1.33   √ 64 2.76  √ 100 5.16
31 .5 1.50  68 3.00 104 5.50
 √ 32 1.53   √ 73 .5 3.28 110 6.00
 √ 33 1.57 


Sulphuretted hydrogen.—This substance solidifies at 122° Fahr. below 0°, and is then a white crystalline translucent substance, not remaining clear and transparent in the solid state like water, carbonic acid, nitrous oxide, &c., but forming a mass of confused crystals like common salt or nitrate of ammonia, solidified from the melted state. As it fuses at temperatures above -122°, the solid part sinks freely in the fluid, indicating that it is considerably heavier. At this temperature the pressure of its vapour is less than one atmosphere, not more, probably, than 0.8 of an atmosphere, so that the liquid allowed to evaporate in the air would not solidify as carbonic acid does.

The following is a table of the tension of its vapour, the marked numbers being close to experimental results, and the rest interpolated. The curve resulting from these numbers, though coming out nearly identical in different series of experiments, is apparently so different in its character from that of water or carbonic acid, as to leave doubts on my mind respecting it, or else of the

  1. Bibliothèque Universelle, 1839, xxiii. p. 185.