Page:The chemical history of a candle.djvu/19

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STEARIN CANDLES.
17

the fat of the ox—Russian tallow, I believe, employed in the manufacture of these dips, which Gay Lussac, or some one who entrusted him with his knowledge, converted into that beautiful substance, stearin, which you see lying beside it. A candle, you know, is not now a greasy thing like an ordinary tallow candle, but a clean thing, and you may almost scrape off and pulverise the drops which fall from it without soiling anything. This is the process he adopted ([1]):—The fat or tallow is first boiled with quick-lime, and made into a soap, and then the soap is decomposed by sulphuric acid, which takes away the lime, and leaves the fat re-arranged as stearic acid, whilst a quantity of glycerin is produced at the same time. Glycerin—absolutely a sugar, or a substance similar to sugar—comes out of the tallow in this chemical change. The oil is then pressed out of it; and you see here this series of pressed cakes, shewing how beautifully the impurities are carried out by the oily part as the pressure goes on increasing, and at last you have left that substance which is melted, and cast into candles as here represented. The candle I have in my hand is a stearin candle,

  1. The fat or tallow consists of a chemical combination of fatty acids with glycerine. The lime unites with the palmitic, oleic, and stearic acids, and separates the glycerine. After washing, the insoluble lime soap is decomposed with hot dilute sulphuric acid. The melted fatty acids thus rise as an oil to the surface, when they are decanted. They are again washed and cast into thin plates, which, when cold, are placed between layers of cocoa-nut matting, and submitted to intense hydraulic pressure. In this way the soft oleic acid is squeezed out, whilst the hard palmitic and stearic acids remain. These are further purified by pressure at a higher temperature, and washing in warm dilute sulphuric acid, when they are ready to be made into candles. These acids are harder and whiter than the fats from which they were obtained, whilst at the same time they are cleaner and more combustible.