Page:The fundamental laws of electrolytic conduction.djvu/18

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MEMOIRS ON THE FUNDAMENTAL

On plunging the zinc and platina wires five-eighths of an inch deep into the acid, and retaining them there for eight beats of the watch (after which they were quickly withdrawn), the needle was deflected, and continued to advance in the same direction some time after the voltaic apparatus had been removed from the acid. It attained the five-and-a-half division, and then returned, swinging an equal distance on the other side. This experiment was repeated many times, and always with the same result.

Hence, as an approximation, and judging from magnetic force only at present, it would appear that two wires, one of platina and one of zinc, each one-eighteenth of an inch in diameter, placed five-sixteenths of an inch apart and immersed to the depth of five-eighths of an inch in acid, consisting of one drop oil of vitrol and four ounces distilled water, at a temperature of about 60º, and connected at the other extremities by a copper wire eighteen feet long and one-eighteenth of an inch thick (being the wire of the galvanometer coils), yield as much electricity in eight beats of my watch, or in 8/150 of a minute, as the electrical battery charged by thirty turns of the large machine in excellent order. Notwithstanding this apparently enormous disproportion, the results are perfectly in harmony with those effects which are known to be produced by variations in the intensity and quantity of the electric fluid.

In order to procure a reference to chemical action, the wires were now retained immersed in the acid to the depth of five-eighths of an inch, and the needle, when stationary, observed; it stood, as nearly as the unassisted eye could decide, at 5 1/3 division. Hence a permanent deflection to that extent might be considered as indicating a constant voltaic current, which in eight beats of my watch could supply as much electricity as the electrical battery charged by thirty turns of the machine. The following arrangements and results are selected from many that were made and obtained relative to chemical action. A platina wire, one-twelfth of an inch in diameter, weighing two hundred and sixty grains, had the extremity rendered plain, so as to offer a definite surface equal to a circle of the same diameter as the wire; it was then connected in turn with the conductor of the machine or with the voltaic apparatus, so as always

to form the positive pole, and at the same time retain a perpendicular position, that it might rest with its whole weight upon

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