Page:Collected Physical Papers.djvu/154

From Wikisource
Jump to navigation Jump to search
This page has been validated.
134
MOLECULAR CHANGES BY ELECTRIC WAVES

surface contamination, for any incipient welding will be at once exhibited by the complete coalescence of the drops. The non-discriminative nature of the action is shown in a striking manner in the following experiment. I may mention here that fragments of solid potassium, and in a lesser degree sodium, exhibit an increase of contact-resistance under the action of electric waves. I made a liquid alloy of potassium and sodium, and drops of this alloy were allowed to float on the stratum separating dense Rangoon oil from lighter kerosene, the alloy being of an intermediate density. The drops coalesced when placed in an intense alternating electric field. The next experiment was made with potassium heated under melted (hard) paraffin. By stirring the molten K with a glass rod, the metal was broken up into numerous spherical drops. These also coalesced under similar electric influence. It is, however, to be borne in mind (1) that in the above experiment the substance is in the form of a liquid, and that in this particular condition certain important molecular changes, to be presently described, cannot very well take place; (2) that the conditions of the experiment are abnormal.

Experiments will be presently described which will show that the observed variation of conductivity produced by radiation is not due to coherence, but to certain molecular changes of an allotropic nature.

Molecular Action.—By this is meant the allotropic modification produced in a substance by the action of electric waves, the allotropic change being due to a difference in the atomic or molecular aggregation. It will be shown that such molecular change does take place