Page:Collected Physical Papers.djvu/163

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COLLECTED PHYSICAL PAPERS
143

suitable compression. The conductivity of the substance is rather small, and therefore a thin stratum should be taken for experiment. The current is observed by means of a sensitive galvanometer. On the application of heat to the tube (which converts the red into the yellow variety), there was at once produced, simultaneously with the molecular transformation, an increase of conductivity. This effect is not due to a rise of temperature, for the increased conductivity was still exhibited on cooling the tube. From this experiment it is seen that the molecular changes can be inferred from changes in the conductivity. In the case described above, the recovery from the B, or second stage, to the first stage, A, is slow; but there may be substances (and there are such substances) where, under the given conditions of temperature and other physical surroundings, the first stage is far more stable than the second; the substance will then pass back quickly from the B condition to the primitive state, on the cessation of the exciting cause which gave rise to the transient B effect. The substance will in this case be "self-recovering."

Electrical Reversal in the Radiation Product

In the hypotheses given above, it was said that the reaction of the radiation product, or B variety, should be opposite to that pf the substance in the normal condition, or in the A state. Thus a negative substance which by the action of radiation shows an increase of resistance during conversion from the A to the B state should exhibit a diminution of resistance when B variety is acted on by electric waves. The contrary would be the case with positive substances.