Page:EB1911 - Volume 12.djvu/369

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352
GRANITE
  

focus or deep-seated source. Towards their margins these granite outcrops often show modifications by which they pass into diorite or syenite, &c.; they may also be finer grained (like porphyries) or rich in tourmaline, or intersected by many veins of pegmatite. From the main granite dikes or veins often run out into the surrounding rocks, thus proving that the granite is intrusive and has forced its way upwards by splitting apart the strata among which it lies. Further evidence of this is afforded by the alteration which the granite has produced through a zone which varies from a few yards to a mile or more in breadth around it. In the vicinity of intrusive granites slates become converted into hornfelses containing biotite, chiastolite or andalusite, sillimanite and a variety of other minerals; limestones recrystallize as marbles, and all rocks, according to their composition, are more or less profoundly modified in such a way as to prove that they have been raised to a high temperature by proximity to the molten intrusive mass. Where exposed in cliffs and other natural sections many granites have a rudely columnar appearance. Others weather into large cuboidal blocks which may produce structures resembling cyclopean masonry. The tors of the west of England are of this nature. These differences depend on the disposition of the joint cracks which traverse the rock and are opened up by the action of frost and weathering.

The majority of granites are so coarse in grain that their principal component minerals may be identified in the hand specimens by the unaided eye. The felspar is pearly, white or pink, with smooth cleaved surfaces; the quartz is usually transparent, glassy with rough irregular fractures; the micas appear as shining black or white flakes. Very coarse granites are called pegmatite or giant granite, while very fine granites are known as microgranites (though the latter term has also been applied to certain porphyries). Many granites show pearly scales of white mica; others contain dark green or black hornblende in small prisms. Reddish grains of sphene or of garnet are occasionally visible. In the tourmaline granites prisms of black schorl occur either singly or in stellate groups. The parallel banded structures of many granites, which may be original or due to crushing, connect these rocks with the granite gneisses or orthogneisses.

Under the microscope the felspar is mainly orthoclase with perthite or microcline, while a small amount of plagioclase (ranging from oligoclase to albite) is practically never absent. These minerals are often clouded by a deposit of fine mica and kaolin, due to weathering. The quartz is transparent, irregular in form, destitute of cleavage, and is filled with very small cavities which contain a fluid, a mobile bubble and sometimes a minute crystal. The micas, brown and white, are often in parallel growth. The hornblende of granites is usually pale green in section, the augite and enstatite nearly colourless. Tourmaline may be brown, yellow or blue, and often the same crystal shows zones of different colours. Apatite, zircon and iron oxides, in small crystals, are always present. Among the less common accessories may be mentioned pinkish garnets; andalusite in small pleochroic crystals; colourless grains of topaz; six-sided compound crystals of cordierite, which weather to dark green pinite; blue-black hornblende (riebeckite), beryl, tinstone, orthite and pyrites.

The sequence of crystallization in the granites is of a normal type, and may be ascertained by observing the perfection with which the different minerals have crystallized and the order in which they enclose one another. Zircon, apatite and iron oxides are the first; their crystals are small, very perfect and nearly free from enclosures; they are followed by hornblende and biotite; if muscovite is present it succeeds the brown mica. Of the felspars the plagioclase separates first and forms well-shaped crystals of which the central parts may be more basic than the outer zones. Last come orthoclase, quartz, microcline and micropegmatite, which fill up the irregular spaces left between the earlier minerals. Exceptions to this sequence are unusual; sometimes the first of the felspars have preceded the hornblende or biotite which may envelop them in ophitic manner. An earlier generation of felspar, and occasionally also of quartz, may be represented by large and perfect crystals of these minerals giving the rock a porphyritic character.

Many granites have suffered modification by the action of vapours emitted during cooling. Hydrofluoric and boric emanations exert a profound influence on granitic rocks; their felspar is resolved into aggregates of kaolin, muscovite and quartz; tourmaline appears, largely replacing the brown mica; topaz also is not uncommon. In this way the rotten granite or china stone, used in pottery, originates; and over considerable areas kaolin replaces the felspar and forms valuable sources of china clay. Veins of quartz, tourmaline and chlorite may traverse the granite, containing tinstone often in workable quantities. These veins are the principal sources of tin in Cornwall, but the same changes may appear in the body of the granite without being restricted to veins, and tinstone occurs also as an original constituent of some granite pegmatites.

Granites may also be modified by crushing. Their crystals tend to lose their original forms and to break into mosaics of interlocking grains. The latter structure is very well seen in the quartz, which is a brittle mineral under stress. White mica develops in the felspars. The larger crystals are converted into lenticular or elliptical “augen,” which may be shattered throughout or may have a peripheral seam of small detached granules surrounding a still undisintegrated core. Streaks of “granulitic” or pulverized material wind irregularly through the rock, giving it a roughly foliated character.

The interesting structural variation of granite in which there are spheroidal masses surrounded by a granitic matrix is known as “orbicular granite.” The spheroids range from a fraction of an inch to a foot in diameter, and may have a felspar crystal at the centre. Around this there may be several zones, alternately lighter and darker in colour, consisting of the essential minerals of the rock in different proportions. Radiate arrangement is sometimes visible in the crystals of the whole or part of the spheroid. Spheroidal granites of this sort are found in Sweden, Finland, Ireland, &c. In other cases the spheroids are simply dark rounded lumps of biotite, in fine scales. These are probably due to the adhesion of the biotite crystals to one another as they separated from the rock magma at an early stage in its crystallization. The Rapakiwi granites of Finland have many round or ovoidal felspar crystals scattered through a granitic matrix. These larger felspars have no crystalline outlines and consist of orthoclase or microcline surrounded by borders of white oligoclase. Often they enclose dark crystals of biotite and hornblende, arranged zonally. Many of these granites contain tourmaline, fluorite and monazite. In most granite masses, especially near their contacts with the surrounding rocks, it is common to find enclosures of altered sedimentary or igneous materials which are more or less dissolved and permeated by the granitic magma.

The chemical composition of a few granites from different parts of the world is given below:—

SiO2. Al2O3. Fe2O3. FeO. MgO. CaO. Na2O. K2O.
I. 74·69 16·21 .. 1·16 0·48 0·28 1·18 3·64
II. 71·33 11·18 3·96 1·45 0·88 2·10 3·51 3·49
III. 72·93 13·87 1·94 0·79 0·51 0·74 3·68 3·74
IV. 76·12 12·18 1·21 0·72 1·12 1·54 2·55 3·21
V. 73·90 13·65 0·28 0·42 0·14 0·23 2·53 7·99
VI. 68·87 16·62 0·43 2·72 1·60 0·71 1·80 6·48

I. Carn Brea, Cornwall (Phillips); II. Mazaruni, Brit. Guiana (Harrison); III. Rödö, near Alnö, Vesternorrland, Sweden (Holmquist); IV. Abruzzen, a group of hills in the Riesengebirge (Milch); V. Pikes Peak, Colorado (Matthews); VI. Wilson’s Creek, near Omeo, Victoria (Howitt).

Only the most important components are shown in the table, but all granites contain also small amounts of zirconia, titanium oxide, phosphoric acid, sulphur, oxides of barium, strontium, manganese and water. These are in all cases less than 1%, and usually much less than this, except the water, which may be 2 or 3% in weathered rocks. From the chemical composition it may be computed that granites contain, on an average, 35 to 55% of quartz, 20 to 30% of orthoclase, 20 to 30% of plagioclase felspar (including the albite of microperthite) and 5 to 10% of ferromagnesian