Page:Experimental researches in chemistry and.djvu/262

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1829.]
'On the Manufacture of Optical Glass.
247

heat. The crucibles are of pure porcelain ware, and as thin as they can be obtained. The covers for them are evaporating dishes, considerably larger than the mouths of the crucibles: being turned upside down, they rest, when in their places, upon the neighbouring earthenware plate; not touching the crucibles, but preventing anything from falling. into them, and preventing the vapours from passing into the room. The latter are, by the draught of the chimney, drawn through by the sides of the crucible into the furnace, and carried away up the flue, so as to occasion no annoyance to the operator. The covers are slung by a piece of platinum wire, which, being passed across the middle on the outside, is bent at each end round the edges, so that a rod of iron slightly curved at the extremity easily suffices to remove them when the crucible is to be opened. Great care is always taken to put them in clean situations, and that in their removal nothing shall fall from them into the glass.

27. This furnace is found to be very effectual in its action; being connected with a high flue governed by a damper, great command of the temperature is obtained. The crucibles before being used are examined as to soundness; their temperature is raised gradually, and should not be above a dull red heat when the operation commences. The mixture already described (25) is then introduced, and the crucible covered; decomposition of the nitrate of lead instantly commences; the boracic acid loses its water, all the fixed elements unite; and it is remarkable that though a considerable quantity of boracic acid usually sublimes with the water when the latter is driven off from its crystals unmixed with other substances, yet scarcely a trace seems to evaporate in the present instance, in consequence of the presence of the oxide of lead.

28. The beat should not be raised too high or the operation hastened, and then the ebullition will proceed very gradually and favourably, the rough materials being by degrees converted into glass. Before the first charge is entirely melted a second is put in, and when that is fused down, sometimes a third, according to the quantity of glass present and the soundness of the crucible. When all is fused, the temperature is allowed to rise, but not too much, lest action upon the crucible to a serious extent should occur; the glass is then well agitated and mixed by a platinum rake or stirrer, to be described hereafter. Finally,