Page:NIOSH Manual of Analytical Methods - 3800.pdf/9

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ORGANIC AND INORGANIC GASES by FTIR Spectrometry: METHOD 3800, Issue 1, dated 15 March 2003 - Page 9 of 47


TABLE 2. REPRESENTATIVE INFRARED DATA FOR THE COMPOUNDS OF TABLE 1

NOTE: The Limit of Detection (LOD) may vary from laboratory to laboratory, analyst to analyst, instrument to instrument, and day to day. Therefore, any determination of this value should be performed under the same conditions used for sample analysis and reported only with those analyses. It is stressed that the values below are only conservative estimates of the expected performance of this method.

Compound Analytical Region (cm-1) Reference Spectrum Filenamesa LOD at 10mb (ppm) Max. conc. at 10mc
(ppm)
Max. RSAd
(abs-cm-1)
Reference Spectrum Source
Aromatic Hydrocarbons
Benzene 3000 - 3150 015mav01.spc 0.32 149 .0360 EPAe
o-xylene 709 - 781 171mav01.spc 0.65 150 .0444 EPAe
m-xylene 782 - 805 172mav01.spc 1.36 146 .0377 EPAe
p-xylene 749 - 840 173mav01.spc 1.17 151 .0561 EPAe
Styrene 738 - 944 147mav01.spc 1.84 150 .0363 EPAe
Toluene 701 - 768 tolmav01.spc 1.16 463 .0499 EPAe
Aliphatic hydrocarbons
n-Hexane 2778 - 3051 095mav01.spc 0.10 150 .0639 EPAe
Ketones
Acetone 1163 - 1265 192mav01.spc 0.95 148 .0211 EPAe
2-Butanone 1127 - 1235 mekmav01.spc 0.27 463 .0233 3Mf
Alcohols
Methanol 941 - 1100 104mav01.spc 0.28 151 .0447 EPAe
Halogented Hydrocarbons
Methylene Chloride 701 – 789 117mav01.spc 0.31 150 .0620 EPAe
Vinylidene Fluoride 1080 – 1215 dfemav05.spc 0.21 25.7 .0930 3Mf
Trichloroethylene 762 – 966 tcemav01.spc 0.43 464 .1071 3Mf
Tetraflouroethylene 1080 – 1215 tfemav05.spc 0.17 25.7 .0930 3Mf

NIOSH Manual of Analytical Methods, Fourth Edition