Page:Radio-activity.djvu/225

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for a screen exposed to Röntgen rays. Giesel made a screen of platino-cyanide of radio-active barium. The screen, very luminous at first, gradually turned brown in colour, and at the same time the crystals became dichroic. In this condition the luminosity was much less, although the active substance had increased in activity after preparation. Many of the substances which are luminous under the rays from active substances lose this property to a large extent at low temperatures[1].


116. Luminosity of radium compounds. All radium compounds are spontaneously luminous. This luminosity is especially brilliant in the dry haloid salts, and persists for long intervals of time. In damp air the salts lose a large amount of their luminosity, but they recover it on drying. With very active radium chloride, the Curies have observed that the light changes in colour and intensity with time. The original luminosity is recovered if the salt is dissolved and dried. Many inactive preparations of radiferous barium are strongly luminous. The writer has seen a preparation of impure radium bromide which gave out a light sufficient to read by in a dark room. The luminosity of radium persists over a wide range of temperature and is as bright at the temperature of liquid air as at ordinary temperatures. A slight luminosity is observed in a solution of radium, and if crystals are being formed in the solution, they can be clearly distinguished in the liquid by their greater luminosity.


117. Spectrum of the phosphorescent light of radium and actinium. Compounds of radium, with a large admixture of barium, are usually strongly self-luminous. This luminosity decreases with increasing purity, and pure radium bromide is only very feebly self-luminous. A spectroscopic examination of the slight phosphorescent light of pure radium bromide has been made by Sir William and Lady Huggins[2]. On viewing the light with a direct vision spectroscope, there were faint indications of a variation of luminosity at different points along the spectrum. In

  1. Beilby in a recent communication to the Royal Society (Feb. 9 and 23, 1905) has examined in some detail the production of phosphorescence by the β and γ rays of radium and has put forward a theory to account for the different actions observed.
  2. Huggins, Proc. Roy. Soc. 72, pp. 196 and 409, 1903.