order to get a photograph of the spectrum within a reasonable time, they made use of a quartz spectroscope of special design which had been previously employed in a spectroscopic examination of faint celestial objects. After three days' exposure with a slit of 1/450 of an inch in width, a negative was obtained which showed a number of bright lines. The magnified spectrum is shown in Fig. 46A. The lines of this spectrum were found to agree not only in position but also in relative intensity with the band spectrum of nitrogen. The band spectrum of nitrogen and also the spark spectrum[1] of radium are shown in the same figure.
Some time afterwards Sir William Crookes and Prof. Dewar showed that this spectrum of nitrogen was not obtained if the radium was contained in a highly exhausted tube. Thus it appears that the spectrum is due to the action of the radium rays either on occluded nitrogen or the nitrogen in the atmosphere surrounding the radium.
It is very remarkable that a phosphorescent light, like that of radium bromide, should show a bright line spectrum of nitrogen. It shows that radium at ordinary temperatures is able to set up radiations which are produced only by the electric discharge under special conditions.
Sir William and Lady Huggins were led to examine the spectrum of the natural phosphorescent light of radium with the hope that some indications might be obtained thereby of the processes occurring in the radium atom. Since the main radiation from radium consists of positively charged atoms projected with great velocity, radiations must be set up both in the expelled body and in the system from which it escapes.
Giesel[2] observed that the spectrum of the phosphorescent light of actinium consists of three bright lines. Measurements of the wave length were made by Hartmann[3]. The luminosity was very slight and a long exposure was required. The lines observed were
- ↑ The spark spectrum of the radium bromide showed the H and K lines of calcium and also faintly some of the strong lines of barium. The characteristic lines of radium of wave-lengths 3814·59, 3649·7, 4340·6 and 2708·6, as shown by Demarçay and others are clearly shown in the figure. The strong line of wave-length about 2814 is due to radium.
- ↑ Giesel, Ber. d. D. Chem. Ges. 37, p. 1696, 1904.
- ↑ Hartmann, Phys. Zeit. 5, No. 18, p. 570, 1904.
