Page:Radio-activity.djvu/505

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built up of parts, one of which, at least, is the atom of helium. The theory that the heavy atoms are all built up of some simple fundamental unit of matter or protyle has been advanced at various times by many prominent chemists and physicists. Prout's hypothesis that all elements are built up out of hydrogen is an example of this point of view of regarding the subject.

On the disintegration theory, the changes occurring in the radio-atoms involve an actual transformation of the atoms through successive changes. This change is so slow in uranium and thorium that at least a million years would be required before the amount of change could be measured by the balance. In radium it is a million times faster, but even in this case it is doubtful whether any appreciable change would have been observed by ordinary chemical methods for many years had not the possibility of such a change been suggested from other lines of evidence.

The similarity of the α particles from the different radio-elements indicates that they consist of expelled particles of the same kind. On this view, helium should be produced by each of the radio-elements. Its presence in minerals containing thorium, for example in monazite sand and the Ceylon mineral described by Ramsay, indicates that helium may be a product of thorium as well as of radium. Strutt[1] has recently suggested that most of the helium observed in radio-active minerals may be a decomposition product of thorium rather than of uranium and radium; for he finds that minerals rich in helium always contain thorium, while many uranium minerals nearly free from thorium contain little helium. The evidence in support of this view is, however, not altogether satisfactory, for some of the uranium minerals in question are secondary uranium minerals (see Appendix B), deposited by the action of water or other agencies at a comparatively late date, and are also, in many cases, highly emanating, and consequently could not be expected to retain more than a fraction of the helium produced in them.

Taking the view that the α particles are projected helium atoms, we must regard the atoms of the radio-elements as compounds of some known or unknown substance with helium. These compounds break up spontaneously, and at a very slow rate even in the

  1. Strutt, Proc. Roy. Soc. March 2, 1905.