Page:The Liquefaction of Gases.djvu/45

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Liquefaction of Gases.
41

hydrogen, hydriodic acid, hydrobromic acid, and even carbonic acid, were obtained, sealed up in tubes in the liquid state; and euchlorine was also secured in a tube receiver with a cap and screw-plug. By using a carbonic acid bath, first cooled in vacuo, there is no doubt other condensed gases could be secured in the same way.

The fluid carbonic acid was supplied to me by Mr. Addams, in his perfect apparatus, in portions of about 220 cubic inches each. The solid carbonic acid, when produced from it, was preserved in a glass; itself retained in the middle of three concentric glass jars, separated from each other by dry jackets of woollen cloth. So effectual was this arrangement, that I have frequently worked for a whole day of twelve and fourteen hours, having solid carbonic acid in the reservoir, and enough for all the baths I required during the whole time, produced by one supply of 220 cubic inches.[1]

By the apparatus, and in the manner, now described, all the gases before condensed were very easily reduced, and some new results were obtained. When a gas was liquefied, it was easy to close the stop-cock, and then remove the condensing tube with the fluid from the rest of the apparatus. But in order to preserve the liquid from escaping as gas, a further precaution was necessary; namely, to cover over the exposed end of the stop-cock by a blank female screw-cap and leaden washer, and also

  1. On one occasion the solid carbonic acid was exceedingly electric, but I could not produce the effect again: it was probably connected with the presence of oil which was in the carbonic acid box; neither it nor the filaments of ice which formed on it in the air conducted, for when touched it preserved its electric state. Believing as yet that the account I have given of the cause of the electric state of an issuing jet of steam and water (Phil. Trans. 1843, p. 17) is the true one, I conclude that this also was a case of the production of electricity simply by friction, and unconnected with vaporization.