Page:The Liquefaction of Gases.djvu/46

From Wikisource
Jump to navigation Jump to search
This page has been validated.
42
Faraday.

to tighten perfectly the screw of the stop-cock plug. With these precautions I have kept carbonic acid, nitrous oxide, fluosilicon, &c., for several days.

Even with gases which could be condensed by the carbonic acid bath in air, this apparatus in the air-pump had, in one respect, the advantage; for when the condensing tube was lifted out of the bath into the air, it immediately became covered with hoar frost, obscuring the view of that which was within; but in vacuo this was not the case, and the contents of the tube could be very well examined by the eye.

Olefiant gas.—This gas condensed into a clear, colourless, transparent fluid, but did not become solid even in the carbonic acid bath in vacuo; whether this was because the temperature was not low enough, or for other reasons referred to in the account of euchlorine, is uncertain.

The pressure of the vapour of this substance at the temperature of the carbonic acid bath in air (-103° Fahr.) appeared singularly uncertain, being on different occasions, and with different specimens, 3.7, 8.7, 5 and 6 atmospheres. The Table below shows the tension of vapour for certain degrees below 0° Fahr., with two different specimens obtained at different times, and it will illustrate this point.

Fahr. Atmospheres. Atmospheres.
°
-100 · · 4.60 · · 9.30
-90 · · 5.68 · · 10.26
-80 · · 6.92 · · 11.33
-70 · · 8.32 · · 12.52
-60 · · 9.88 · · 13.86
-50 · · 11.72 · · 15.36
-40 · · 13.94 · · 17.05
-30 · · 16.56 · · 18.98
-20 · · 19.58 · · 21.23
-10 · · ·  · · · 23.89
-0 · · ·  · · · 27.18
10 · · ·  · · · 31.70
20 · · ·  · · · 36.80
30 · · ·  · · · 42.50